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Beilstein J. Org. Chem. 2014, 10, 1299–1307, doi:10.3762/bjoc.10.131
Graphical Abstract
Figure 1: Chemical structure of the investigated systems. Left: Double bond within the axle; Right: Single bo...
Figure 2: Molecular geometry of one rotaxane optimized in periodic boundaries at the PBE-D3/1000 eV level. Hy...
Figure 3: Electrostatic potential for the complexes 2a@1 (top left), 2e@1 (middle left), 2h@1 (lower left) an...
Figure 4: Interaction energies plotted against the Hammett σ parameters. The values are given in Table 1. Black curv...
Beilstein J. Org. Chem. 2013, 9, 1620–1629, doi:10.3762/bjoc.9.185
Scheme 1: Experimental results for the radical arylation of epoxides.
Scheme 2: 5-exo cyclization of the hexenyl radical.
Scheme 3: Intramolecular radical additions of simple aniline derivatives.
Scheme 4: Successful catalytic radical addition to an N-methyl substituted aniline.
Figure 1: Optimized structure of the transition state of the radical addition of 1 (left: spin density plot a...
Scheme 5: Intramolecular radical additions of simple aniline derivatives.
Scheme 6: Mismatching of polar effects.
Scheme 7: Examples of p-substituted anilines investigated.
Scheme 8: Examples of m,m’-disubstituted anilines investigated.
Scheme 9: Addition reactions leading to dihydrobenzofuran and an indane.